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To our delight, it was possible to generate the aryl-fused BCHep framework 16 (functioning as isosteres of 17 ) via an iridium-catalysed [2+2] photocycloaddition through visible light-induced energy transfer, adapting the methodology developed by Kwon and coworkers 30

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HPLCMS analysis after solubilization with acidified methanol confirmed an almost stoichiometric conversion of 3,4- cis -leucocyanidin ( 6 ) into cyanidin ( 8 ), while the formation of the side products epidihydroquercetin ( 9 ), and quercetin ( 11 ) was reduced (Extended Data Fig

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