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Mol Med Rep (2019) 20(3):256370

While lipophilicity, dipole moment, and size are factors that influence the ability of a compound to enter the hydrophobic core of a cell membrane, the lipid bilayer environment is too chemically complex, fluid, and heterogeneous for these indicators alone to provide accurate estimates of transport kinetics

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While coffee doesn't necessarily "block" glutathione, the acidity of coffee and the presence of other compounds might interfere with the delicate liposomal structure of some supplements